Potassium tert-Butoxide Promoted Intramolecular Mizoroki–Heck-Type Radical Cyclization: Photoluminescence Properties and Application in Live Cancer-Cell Imaging-Reference-Cited by-同舟云学术

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Potassium tert-Butoxide Promoted Intramolecular Mizoroki–Heck-Type Radical Cyclization: Photoluminescence Properties and Application in Live Cancer-Cell Imaging

Published:2022-02-25 Issue:08 Volume:33 Page:785-790
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Sivaraman Mahalingam¹,Maheswari Narayanan Uma¹,Perumal Paramasivan T.¹,Mayakrishnan Sivakalai¹,Balachandran Chandrasekar²³,Aoki Shin²³

Affiliation:

1. Organic & Bioorganic Chemistry, CSIR- Central Leather Research Institute

2. Faculty of Pharmaceutical Sciences, Tokyo University of Science

3. Research Institute for Biomedical Sciences (RIBS), Tokyo University of Science

Abstract

AbstractPrivileged indole-fused phenanthridinones were synthesized by an inexpensive potassium tert-butoxide-promoted intramolecular Mizoroki–Heck-type radical cyclization. This method offers high atom- and step-economic C–C bond formation. An array of the synthesized compounds showed good photoluminescence properties, and could be successfully applied as fluorescent bioprobes for imaging of living cancer cells.

Funder

Council of Scientific and Industrial Research

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1782-7150.pdf

Reference2 articles.

1. Transition-Metal-Free Coupling Reactions

2. Potassium t-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

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