From Enynyl Esters to Functionalized Polycyclic Derivatives via Cycloisomerization and Post-Functionalization-Reference-Cited by-同舟云学术

From Enynyl Esters to Functionalized Polycyclic Derivatives via Cycloisomerization and Post-Functionalization

Published:2016-08-10 Issue:19 Volume:48 Page:3199-3206
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Guelen Simon¹,Blazejak Max¹,Mouriès-Mansuy Virginie¹,Fensterbank Louis¹

Affiliation:

1. Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Universités UPMC Univ Paris 06

Abstract

The post-functionalization of ketone products originating from the PtCl2-catalyzed cycloisomerization of enynyl esters is described. Post-functionalization is accomplished via diastereoselective alkylation, regioselective cyclopropane opening and regioselective Baeyer–Villiger and Beckmann rearrangements to provide functionalized polycycles.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0035-1561488.pdf

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