Aryne Annulations for the Synthesis of Carbocycles and Heterocycles: An Updated Review

Author:

Gogoi Pranjal12,Sarmah Manashi1,Hazarika Hemanta12

Affiliation:

1. Applied Organic Chemistry Group, Chemical Science and Technology Division, CSIR-North East Institute of Science and Technology

2. Academy of Scientific and Innovative Research (AcSIR)

Abstract

AbstractCarbocycles and heterocycles are highly relevant structural moieties that have found countless applications in interdisciplinary areas. In this regard, the interesting chemistry of arynes has been embraced by researchers for the synthesis of structurally different polycyclic systems, i.e. carbocycles and heterocycles. In this review, we intended to provide a comprehensive overview on the annulative approach considering Kobayashi’s aryne intermediate as the key reactive species with diverse nucleophilic and electrophilic partners. The review highlights the different aryne annulation reactions adopted for the synthesis of carbocycles and heterocycles (covering articles mainly from around 2010), showcasing their viability towards broad range of substrates bearing diverse functionalities.1 Introduction2 Synthesis of Carbocycles3 Synthesis of Heterocycles4 Conclusions

Funder

Department of Science and Technology, New Delhi

Science and Engineering Research Board

Council of Scientific and Industrial Research, New Delhi

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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