Nickel-Catalyzed Oxidative Transamidation of Tertiary Aromatic Amines with N-Acylsaccharins-Reference-Cited by-同舟云学术

Nickel-Catalyzed Oxidative Transamidation of Tertiary Aromatic Amines with N-Acylsaccharins

Published:2021-05-25 Issue:16 Volume:32 Page:1642-1646
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Liu Shengzhang¹,Yang Lingyun¹,Wang Tao¹²,Fu Junkai¹²^ORCID,Tao Jiasi¹,Yu Weijie¹

Affiliation:

1. College of Chemistry and Chemical Engineering, Jiangxi Normal University

2. National Research Center for Carbohydrate Synthesis, Jiangxi Province’s Key Laboratory of Chemical Biology, Jiangxi Normal University

Abstract

AbstractThe use of tertiary amines as surrogates for secondary amines has prominent advantages in terms of stabilization and ease of handling. A Ni-catalyzed transamidation of N-acylsaccharins with tertiary aromatic amines is reported. By using tert-butyl hydroperoxide as the terminal oxidant, this reaction permits selective cleavage of the C(sp3)–N bonds of unsymmetrical tertiary aromatic amines depending on the sizes of the alkyl substituents.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1517-5895.pdf

Reference6 articles.

1. Catalytic amide formation from non-activated carboxylic acids and amines

2. Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate