Bridging Chlorine Atoms Enable the Construction of a Novel Benzimidazole-Derived Fluorescent Molecule-Reference-Cited by-同舟云学术

Bridging Chlorine Atoms Enable the Construction of a Novel Benzimidazole-Derived Fluorescent Molecule

Published:2022-03-07 Issue:07 Volume:33 Page:684-688
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Yan Xiangyu¹,Jiang Bowen¹,Chen Cheng¹^ORCID,Yuan Ye¹,Fan Guanggao¹,Zou Yu²,Sang Wei¹

Affiliation:

1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology

2. College of Chemistry, Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University

Abstract

AbstractWe have designed and prepared a novel benzimidazole-based fluorescent molecule through the construction of chlorine bridges. The structure of the molecule was authenticated by means of X-ray crystallography and its photophysical properties (absorption and fluorescence spectra) were investigated. Furthermore, the fluorescence emission of the molecule was rationalized through density functional theory calculations, which showed the influence of the bridging chlorine atoms on the energy levels and energy gap.

Funder

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing

State Key Laboratory of Catalysis

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1790-2858.pdf

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