Tuning StackPhim Ligands: Applications in Enantioselective Borylation and Alkynylation-Reference-Cited by-同舟云学术

Tuning StackPhim Ligands: Applications in Enantioselective Borylation and Alkynylation

Published:2022-01-03 Issue:09 Volume:54 Page:2157-2164
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Aponick Aaron¹^ORCID,Dahiya Gaurav¹^ORCID,Abboud Khalil A.²

Affiliation:

1. Center for Heterocyclic Compounds, Department of Chemistry, University of Florida

2. Center for X-ray Crystallography, Department of Chemistry, University of Florida

Abstract

AbstractHere we present a new stack ligand with a modified imidazoline backbone prepared from cyclohexanediamine. This new stack ligand, Cy-StackPhim, has been found to complement the parent StackPhim ligand in an enantioselective borylation reaction. Additionally, a correlation between the nature of substituents on the imidazoline ring and the substituents on the electrophile is also discussed.

Funder

National Science Foundation

National Institutes of Health

University of Florida

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1730-2473.pdf

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