Practical Transition-Metal-Free Protodeboronation of Arylboronic Acids in Aqueous Sodium Hypochlorite-Reference-Cited by-同舟云学术

Practical Transition-Metal-Free Protodeboronation of Arylboronic Acids in Aqueous Sodium Hypochlorite

Published:2020-10-07 Issue:20 Volume:31 Page:2039-2042
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Li Minxin,Tang Yanling,Mao Zewei¹,Gao Jinchun,Rao Gaoxiong

Affiliation:

1. College of Pharmaceutical Science, Yunnan University of Chinese Medicine

Abstract

AbstractA concise and practical method was developed for the protodeboronation of arylboronic acids under mild conditions in aqueous NaClO at 100 °C. The strategy is low-cost, transition-metal-free, and base-free.

Funder

Yunnan Provincial Science and Technology Department

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1706298.pdf

Reference6 articles.

1. CCLXXX.—Studies of the boron–carbon linkage. Part I. The oxidation and nitration of phenylboric acid

2. Selective protodeboronation: synthesis of 4-methyl-2-thiopheneboronic anhydride and demonstration of its utility in Suzuki–Miyaura reactions

3. In SituGenerated Palladium Nanoparticles for Catalytic Dehalogenation of Aryl Halides and Deboronation of Arylboronic acids

4. Copper-catalyzed protodeboronation of arylboronic acids in aqueous media

5. Base-promoted silver-catalyzed protodeboronation of arylboronic acids and esters

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