Author:
Ogoshi Sensuke,Ishida Naoyoshi,Iwamoto Hiroaki,Sunagawa Denise Eimi,Ohashi Masato
Abstract
AbstractA catalytic method for the synthesis of pentafluoroethyl ketones has been developed. The cesium fluoride catalyst can be used to convert acyl fluorides into the pentafluoroethyl ketones under tetrafluoroethylene pressure without generating stoichiometric quantities of chemical waste. Mechanistic studies suggest that high reaction temperature is crucial for the ketone to be the major product.
Funder
Japan Society for the Promotion of Science
Subject
Organic Chemistry,Catalysis
Cited by
9 articles.
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