Electrochemical Synthesis of Vinyl Sulfones by Sulfonylation of Styrenes with a Catalytic Amount of Potassium Iodide-Reference-Cited by-同舟云学术

Electrochemical Synthesis of Vinyl Sulfones by Sulfonylation of Styrenes with a Catalytic Amount of Potassium Iodide

Published:2020-08-26 Issue:17 Volume:31 Page:1720-1724
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Gao Hui¹,Li Pin-Hua¹,Wang Pei-Long¹²,Jiang Zhi-Sheng¹,Li Chao¹,Tian Zhi-Ao¹

Affiliation:

1. Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education, Department of Chemistry, Huaibei Normal University

2. Information College, Huaibei Normal University

Abstract

An electrochemical sulfonylation reaction of styrenes was developed in which sodium arylsulfinates were used as sulfonylating reagents, a catalytic amount of KI was used as a redox mediator, and Bu4NBF4 was used as the electrolyte. In addition to various styrenes, sodium arylsulfinates with either electron-donating or electron-withdrawing groups were tolerated.

Funder

Natural Science Foundation of Anhui Province

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1707249.pdf

Reference8 articles.

1. Stereoselective Synthesis of (E)-Alkenyl Sulfones from Alkenes or Alkynes via Copper-Catalyzed Oxidation of Sodium Sulfinates

2. E-Selective synthesis of vinyl sulfones via silver-catalyzed sulfonylation of styrenes

3. An efficient one-pot synthesis of vinyl sulphones via CAN mediated reaction of aryl sulphinates and alkenes