Affiliation:
1. State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology
2. State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University
Abstract
Hydrosilylation of multiple carbon–carbon bonds is a well-known process for the construction of organosilicon compounds. Nowadays, precious metal catalysts, especially platinum complexes, still occupy dominant positions in such processes. However, one important member of the precious metal family, iridium, is less used in this field. As early research mainly focused on developing stable and effective iridium catalysts, recent advances have disclosed the specific efficiency of simple iridium catalytic systems in the synthesis of functional organosilicon compounds. This short review summarizes the utilization of iridium complexes for the hydrosilylation of alkenes and alkynes, with an emphasis on the recent advances published in the last decade.1 Introduction2 Iridium-Catalyzed Hydrosilylation of Alkenes3 Iridium-Catalyzed Hydrosilylation of Alkynes4 Conclusions and Perspectives
Funder
National Natural Science Foundation of China
Beijing University of Chemical Technology
Fundamental Research Funds for the Central Universities
State Key Laboratory of Natural and Biomimetic Drugs
Subject
Organic Chemistry,Catalysis
Cited by
22 articles.
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