Affiliation:
1. Faculty of Chemistry, Adam Mickiewicz University in Poznań
2. Centre for Advanced Technologies, Adam Mickiewicz University in Poznań
Abstract
Herein, we present application of α-amino-β-fluorophosphonates for the construction of their dipeptide analogues. α-Amino-β-fluorophosphonates were prepared in a XtalFluor-E mediated deoxyfluorination of α-hydroxy-β-aminophosphonates. The reaction proceeds through an aziridinium ion formation, which was confirmed by the formation of a hexacoordinate phosphorus compound. Moreover, the absolute configuration of the obtained compounds was determined by X-ray analysis, which proved the stereochemistry.
Subject
Organic Chemistry,Catalysis
Cited by
6 articles.
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