Affiliation:
1. Institute for Organic Chemistry and Macromolecular Chemistry, Heinrich-Heine-Universität Düsseldorf
Abstract
A comparison of two catalytic, metal-free iodoperfluoroalkylation protocols is presented. Frustrated Lewis pairs [
t
Bu3P/B(C6F5)3] or phosphines/phosphites under visible light irradiation efficiently mediate the functionalization of non-activated alkenes and alkynes. A comprehensive account of the corresponding substrate scopes as well as insights into the mechanistic details of both reaction pathways are provided.
Funder
Deutsche Forschungsgemeinschaft
Studienstiftung des deutschen Volkes
Subject
Organic Chemistry,Catalysis
Cited by
17 articles.
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