Potassium tert-Butoxide Mediated Reductive C–P Cross-Coupling of Arylvinyl Sulfides through C

Potassium tert-Butoxide Mediated Reductive C–P Cross-Coupling of Arylvinyl Sulfides through C–S Bond Cleavage

Published:2020-10-13 Issue:02 Volume:32 Page:224-228
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Zeng Qingle¹^ORCID,Feng Jie¹,Zhang Qiaoling¹,Li Fuhai¹,Yang Lu²,Kuchukulla Ratnakar Reddy¹

Affiliation:

1. State Key Laboratory of Geohazard Prevention and Geoenvironment Protection, College of Materials, Chemistry and Chemical Engineering, Chengdu University of Technology

2. Department of Chemistry, Graduate School of Science, Tohoku University

Abstract

AbstractA transition-metal-free t-BuOK-mediated reductive C–P cross-coupling reaction of arylvinyl sulfides with diarylphosphine oxides through C–S bond cleavage has been developed. This protocol not only permits the synthesis of diaryl(2-arylethyl)phosphine oxides, but also achieves an unprecedented construction of a C–P bond through C–S bond cleavage and reduction of a C–C double bond in one pot.

Funder

State Key Laboratory of Geohazard Prevention and Geoenvironment Protection

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1707319.pdf

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