Porphyrinoids with Vinylene Bridges

Author:

Kuzuhara Daiki1,Yamada Hiroko2

Affiliation:

1. Faculty of Science and Engineering, Iwate University

2. Graduate School of Science and Technology, Nara Institute of Science and Technology (NAIST)

Abstract

AbstractPorphyrinoids containing vinylene bridges, such as triphyrin(2.1.1), porphycene, porphyrin(2.1.2.1), and hexaphyrin(2.1.2.1.2.1), are a relatively new family of porphyrinoids. Vinylene bridges give porphyrinoids a lower symmetry and a flexibility of the framework and they permit cis/trans-isomerization reactions; these factors confer unique properties to these substances, such as coordination to metal ions and aromaticity switching. In this account, the synthesis, crystal structures, and properties of new porphyrinoids containing vinylene bridges are summarized.1 Introduction2 Triphyrin(2.1.1)3 Porphycene4 Porphyrin(2.1.2.1)5 Hexaphyrin(2.1.2.1.2.1)6 Conclusion

Funder

Japan Society for the Promotion of Science

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

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3. Recent progress in porphycenes synthesis;Journal of Porphyrins and Phthalocyanines;2022-11-12

4. Development of the design, synthesis and property of porphyrin arrays and porphyrinoids;SCIENTIA SINICA Chimica;2022-07-29

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