Affiliation:
1. Department of Chemistry for Materials, Graduate School of Engineering
2. School of Energy Science and Engineering
Abstract
AbstractAn umpolung reaction of α-tosyloximino esters in a flow system is disclosed. Tandem N,N-dialkylations with two different Grignard reagents gave the desired N,N-dialkylated products in moderate to good yields. In addition, a tandem N,N,C-trialkylation of an α-tosyloximino ester with three different Grignard reagents has been successfully achieved to afford the desired N,N,C-trialkylated product in moderate yield.
Funder
Japan Society for the Promotion of Science
Cited by
4 articles.
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