Co(OAc)2/TBHP as a Highly Active Catalytic System for the Selective Oxidation of Aromatic Amines to Nitro Derivatives

Author:

Yin Weiyan123,Yu Junxia1,Wu Liqiong12,Yao Lifeng4

Affiliation:

1. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology

2. Hubei Key Laboratory of Biomass Fibers and Eco-dyeing & Finishing, School of Chemistry and Chemical Engineering, Wuhan Textile University

3. State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control, Wuhan University of Science and Technology

4. School of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University

Abstract

AbstractAn efficient cobalt-catalyzed protocol for the selective oxidation of anilines using a combination of inexpensive tert-butyl hydroperoxide and Co(OAc)2·4H2O without any ligand has been developed, providing the nitroarene products in good to excellent yields (up to 96%).

Funder

National Natural Science Foundation of China

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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