Amine Oxidation by Electrochemically Generated Peroxodicarbonate-Reference-Cited by-同舟云学术

Amine Oxidation by Electrochemically Generated Peroxodicarbonate

Published:2022-05-24 Issue:15 Volume:33 Page:1527-1531
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Gooßen Lukas J.¹,Seitz Ann-Katrin¹,van Lingen Tim¹,Dyga Marco¹,Kohlpaintner Philipp J.²,Waldvogel Siegfried R.²^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Ruhr-Universität Bochum

2. Department of Chemistry, Johannes Gutenberg Universität Mainz

Abstract

AbstractThe N-oxidation of tertiary amines was achieved by using electrochemically generated peroxodicarbonate solutions as sustainable oxidizers. The presence of EDTA and 2,2,2-trifluoroacetophenone as a mediator was found to be crucial for converting water-insoluble substrates. Various tertiary amines were converted into their corresponding N-oxides in yields of up to 98%. The scope includes economically important surfactants and potential platform oxidizers.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1860-3405.pdf

Reference8 articles.

1. High Production Volume Chemical Amine Oxides [C8-C20] Category Environmental Risk Assessment

2. On the preparation of amine N-oxides by using dioxiranes

3. Percarbonate