Author:
Kotha Sambasivarao,Chaurasia Usha Nandan
Abstract
AbstractThe synthesis of various highly functionalized caged systems suitable as high energy density materials, which were assembled by utilization of an olefin cross-metathesis strategy, is reported. E-Selectivity was observed during the cross-metathesis by using Grubbs second generation catalyst (G-II) and N-tolyl Grubbs catalyst in most of the cross-metathesis products. The stereochemistry of the olefin formed during the cross-metathesis has been determined unambiguously by a single-crystal X-ray diffraction study.
Funder
Defense Research and Development Organisation
Subject
Organic Chemistry,Catalysis
Cited by
2 articles.
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