Synthesis of Chiral Triazole-Based Halogen Bond Donors

Author:

Kaasik MikkORCID,Kaabel Sandra,Kriis Kadri,Järving Ivar,Kanger Tõnis1ORCID

Affiliation:

1. Department of Chemistry and Biotechnology, School of Science, Tallinn University of Technology

Abstract

The number of applications that use halogen bonding in the fields of self-assembly, supramolecular aggregation, and catalysis is growing. However, the accessibility of chiral halotriazoles shows that there is still a lot more to explore. The simple click-chemistry is applied for the straightforward synthesis of enantiomerically pure mono- and bidentate as well as multifunctional iodotriazole-based XB donors. The methodology is characterized by a wide variability due to easy access of chiral azides.

Funder

Haridus- ja Teadusministeerium

Tartu Ülikool

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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