Green Synthesis of Haloformates from Olefins Using Formic Acid as Reactant, Protonic Acid, and Solvent-Reference-Cited by-同舟云学术

Green Synthesis of Haloformates from Olefins Using Formic Acid as Reactant, Protonic Acid, and Solvent

Published:2018-06-07 Issue:12 Volume:29 Page:1611-1616
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Wang Ligeng¹^ORCID,Hu Jun¹,Zhang Hualong¹,Yu Qin¹,Feng Chun¹

Affiliation:

1. College of Chemical Engineering, Zhejiang University of Technology

Abstract

Bromoformates and iodoformates are successfully synthesized in high yields with regioselectivity and stereoselectivity by using ZnAl-BrO3 – layered double hydroxides (LDHs) and KX (X = Br, I) in the presence of formic acid (HCOOH). The protocol exploits the versatile function of formic acid as solvent, nucleophilic reagent, and acidic medium simultaneously, simplifying the reaction and separation of the products.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0037-1610028.pdf

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