Affiliation:
1. Organic Synthesis and Process Chemistry Division, CSIR-Indian Institute of Chemical Technology
2. Academy of Scientific and Innovative Research (AcSIR)
Abstract
The first asymmetric total synthesis of penicillinolide A is described. Key steps of the synthesis involve Jacobsen’s hydrolytic kinetic resolution (HKR), chelation controlled allylation, Brown’s asymmetric allylation, hydroboration, and Yamaguchi lactonization.
Subject
Organic Chemistry,Catalysis
Cited by
7 articles.
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