Affiliation:
1. RWTH Aachen University, Institute of Organic Chemistry
Abstract
The rearrangement reaction of ammonium ylides furnishes valuable α,α-disubstituted amino esters. In this work, we describe the visible-light photolysis reaction of aryldiazoacetates in the presence of tertiary amines that react via a free ammonium ylide in a sigmatropic rearrangement reaction to provide amino esters in moderate to very good yields (33 examples, up to 97% yield).
Funder
Deutsche Forschungsgemeinschaft
Subject
Organic Chemistry,Catalysis
Cited by
12 articles.
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