Affiliation:
1. Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226
Abstract
For some aromatics, a twofold C–H deprotolithiation can be achieved, allowing these compounds to be subsequently difunctionalized in one step. This short review brings together examples in which ferrocenes are converted in this way.1 Introduction2 Bare Ferrocene3 Ferrocenes Substituted by Alkyl or Silyl Groups4 Ferrocenes Substituted by Aminoalkyls5 Ferrocenes Substituted by Halogens or Oxygen-Based Groups6 Ferrocenes Substituted by Alkoxyalkyls or Acetals7 Ferrocenes Substituted by Sulfoxides8 Ferrocenes Substituted by Oxazolines9 Ferrocenes Substituted by Carboxamides10 Conclusion
Subject
Organic Chemistry,Catalysis
Cited by
13 articles.
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1. From ferrocene to decasubstituted enantiopure ferrocene-1,1′-disulfoxide derivatives;Dalton Transactions;2023
2. Stereoselective Synthesis of 1,1’,2,2’‐Tetrasubstituted Ferrocenes by Double Lithiation of a 1,1’‐Disubstituted Ferrocenyl Pyrroloimidazolone;European Journal of Inorganic Chemistry;2022-12-19
3. Advanced Application of Planar Chiral Heterocyclic Ferrocenes;Inorganics;2022-09-23
4. Sitting Out the Halogen Dance. Room-Temperature Formation of 2,2′-Dilithio-1,1′-dibromoferrocene. TMEDA and Related Lithium Complexes: A Synthetic Route to Multiply Substituted Ferrocenes;Organometallics;2021-09-22
5. Synthetic Route to 1,1′,2,2′-Tetraiodoferrocene That Avoids Isomerization and the Electrochemistry of Some Tetrahaloferrocenes;Organometallics;2021-07-23