New Cyano-Group-Containing 1,3-Oxaselenoles: Nucleophilic Substitution of a Cyano Group with Rearrangement-Reference-Cited by-同舟云学术

New Cyano-Group-Containing 1,3-Oxaselenoles: Nucleophilic Substitution of a Cyano Group with Rearrangement

Published:2018-08-24 Issue:15 Volume:29 Page:2035-2038
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Kachanov Andrey¹,Zamaraev Andrey²,Gerasimenko Andrey³,Maslov Konstantin¹,Slabko Oleg¹,Kaminskii Vladimir¹

Affiliation:

1. Far Eastern Federal University, School of Natural Sciences

2. G. B. Elyakov Pacific Institute of Bioorganic Chemistry, Far East Branch of the Russian Academy of Sciences

3. Institute of Chemistry, Far East Branch of the Russian Academy of Sciences

Abstract

New cyano-group-containing 1,3-oxaselenoles were obtained by the treatment of aroylacetonitriles with selenium(IV) oxide. The resulting products were shown to react with ammonia, hydrazine, or primary amines; this reaction was accompanied by aryl rearrangement.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0037-1609939.pdf

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