Affiliation:
1. Department of Chemistry, Graduate School of Science, OsakaPrefecture University
2. Department of Applied Chemistry, National Chiao Tung University
Abstract
The C(sp3)–H allylation of alkanes is investigated by using allyl bromides under radical reaction conditions. In many cases, methine C–H allylation preceded methylene and methyl C–H allylation with complete or a high degree of site selectivity. The C–H allylation of allylic compounds, such as allylbenzene, gives 1,5-dienes with the SH2′ reactions of the allyl radicals occurring at the less hindered carbon.
Funder
Japan Society for the Promotion of Science
Ministry of Education, Culture, Sports, Science and Technology
Subject
Organic Chemistry,Catalysis
Cited by
13 articles.
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