Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System
Author:
Debnath Sudarshan,
Mondal Shovan1ORCID
Affiliation:
1. Department of Chemistry, Syamsundar College
Abstract
Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8-peri-interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides support for the influence of the 1,8-peri-interaction.
Funder
Science and Engineering Research Board
Publisher
Georg Thieme Verlag KG
Subject
Organic Chemistry,Materials Science (miscellaneous),Biomaterials,Catalysis