Abstract
AbstractIt has been established that the dienylation of unfunctionalized arenes with 1,6-diynes, possessing aryl groups at the diyne termini, proceeds to give the corresponding dienylated arenes in the presence of a catalytic amount of an electron-deficient cyclopentadienyl rhodium(III) complex, [CpERhCl2]2, and a stoichiometric amount of silver carbonate. Experimental and theoretical mechanistic studies revealed that a CpERh(I) complex generated in situ might catalyze the present dienylation reaction.
Funder
Japan Society for the Promotion of Science
Subject
Organic Chemistry,Catalysis
Cited by
5 articles.
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