Affiliation:
1. Department of Chemistry, School of Physical and Decision Sciences, Babasaheb Bhimrao Ambedkar University (A Central University)
2. Department of Biological and Synthetic Chemistry, Centre of Biomedical Research
Abstract
AbstractA metal and additive-free stereospecific direct N-H and N-Me aziridination of inactivated olefins is disclosed using N-Boc-O-tosylhydroxylamine (TsONHBoc) as an aminating agent in hexafluoroisopropanol (HFIP). The use of TsONHBoc, which generates the free aminating agent in situ under the reaction conditions, has several inherent advantages over other similar agents, such as low cost, easy access, and stability (non-explosiveness) during storage over a longer time.
Funder
University Grants Commission – Basic Scientific Research
Science and Engineering Research Board
Subject
Organic Chemistry,Catalysis
Cited by
9 articles.
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