Catalytic Reductive Cleavage of Poly(phenylene sulfide) Using a Hydrosilane-Reference-Cited by-同舟云学术

Catalytic Reductive Cleavage of Poly(phenylene sulfide) Using a Hydrosilane

Published:2021-05-27 Issue:18 Volume:53 Page:3351-3354
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Minami Yasunori¹²,Nakajima Yumiko¹²,Matsuyama Nao¹,Matsuo Yasuaki²³,Tamura Masanori¹²,Sato Kazuhiko¹

Affiliation:

1. Interdisciplinary Research Center for Catalytic Chemistry (IRC3), National Institute of Advanced Industrial Science and Technology (AIST)

2. DIC-AIST Cooperative Research Laboratory for Sustainability and Materials, National Institute of Advanced Industrial Science and Technology (AIST)

3. Central Research Laboratories, DIC Corporation

Abstract

AbstractThe solvent-insoluble poly(phenylene sulfide) main chain was reductively cleaved by using triethylsilane as a hydrogen source under palladium/IcHex catalytic conditions. After the reaction, benzene and bis(triethylsilyl) sulfide as a sulfide source were formed efficiently. This method could be operated on a gram scale.

Funder

Japan Society for the Promotion of Science

National Institute of Advanced Industrial Science and Technology

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1518-9010.pdf

Reference9 articles.

1. Hydrogenolysis of Sulfur Compounds by Raney Nickel Catalyst

2. Formic acid and the high-temperature reductive desulfurization of aromatic sulfides