Rhodium-Catalyzed Ring Expansion and Ring Opening of Azetidines: Domino Conjugate Addition/Inert-Bond Activation-Reference-Cited by-同舟云学术

Rhodium-Catalyzed Ring Expansion and Ring Opening of Azetidines: Domino Conjugate Addition/Inert-Bond Activation

Published:2022-08-02 Issue:01 Volume:34 Page:14-22
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Xie Jian-Bo¹²^ORCID,Sun Ling-Zhi¹

Affiliation:

1. Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Chemistry and Pharmacy, Northwest A&F University

2. Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology

Abstract

AbstractDomino conjugate addition/inert-bond activation is a useful strategy for improving the efficiency of synthesis. We summarize reports on domino conjugate addition/inert-bond activation and its applications in the rhodium-catalyzed ring-expansion and ring-opening reactions of azetidines.1 Introduction2 Rhodium-Catalyzed Domino Conjugate Addition/β-C Cleavage/ Protonation3 Rhodium-Catalyzed Domino Conjugate Addition/N-Directed α-C(sp3)–H Activation4 Conclusion

Funder

National Natural Science Foundation of China

Guangdong Provincial Key Laboratory of Catalysis

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1915-8491.pdf

Reference8 articles.

1. Rhodium-Catalyzed Asymmetric 1,4-Addition of Sodium Tetraarylborates to β,β-Disubstituted α,β-Unsaturated Esters

2. Double 1,4-rhodium migration cascade in rhodium-catalysed arylative ring-opening/spirocyclisation of (3-arylcyclobutylidene)acetates

3. Synthesis of β,β-Disubstituted Indanones via the Pd-Catalyzed Tandem Conjugate Addition/Cyclization Reaction of Arylboronic Acids with α,β-Unsaturated Esters

4. Rhodium catalyzed C–C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

5. Rhodium-Catalyzed Ring Expansion of Azetidines via Domino Conjugate Addition/N-Directed α-C(sp³)–H Activation

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