Recent Advances in Electrochemically Mediated Reactions of Diselenides

Author:

Mo Zu-Yu1,Pan Ying-Ming2,Zhan Lei1,Wang Qian2,Tang Hai-Tao2ORCID

Affiliation:

1. Guangxi Key Laboratory of Drug Discovery and Optimization, Guangxi Engineering Research Center for Pharmaceutical Molecular Screening and Druggability Evaluation, Pharmacy School of Guilin Medical University

2. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences of Guangxi Normal University

Abstract

AbstractOrganoselenium compounds are crucial molecules that are utilized extensively in diverse fields such as medicine, agriculture, catalysis, and organic materials. The incorporation of selenium atoms into organic molecules holds significant importance in synthetic chemistry. Organic electrochemical synthesis, a green, mild, and efficient strategy, has displayed remarkable potential for organoselenium chemistry synthesis. Consequently, there has been substantial interest in recent years in researching electrochemically mediated synthesis of organoselenium compounds. This review provides an overview of the progress made in electrochemically mediated organic selenium reactions over the last decade, including electrochemical mediated selenium catalysis, electrochemical oxidation of diselenide coupling, and electrochemical oxidation tandem selenocyclization. The scope, limitations, and mechanisms of those reactions are emphasized.1 Introduction2 Electrochemical Selenium-Catalyzed Reactions3 Electrochemically Mediated Coupling of Aromatic/Heterocyclic Rings with Diselenides4 Electrochemically Mediated Tandem Selenocyclization5 Conclusion

Funder

Natural Science Foundation of Guangxi Province

Guangxi Normal University

Middle-aged and Young Teachers’ Basic Ability Promotion Project of Guangxi

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Materials Science (miscellaneous),Biomaterials,Catalysis

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