Halonium Catalysis: An Underutilized and Underexplored Catalytic Concept in Olefin Functionalizations-Reference-Cited by-同舟云学术

Halonium Catalysis: An Underutilized and Underexplored Catalytic Concept in Olefin Functionalizations

Published:2020-10-02 Issue:06 Volume:32 Page:539-544
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Li Wei¹^ORCID,Gembreska Nathan R.,Vogel Alexander K.,Ziegelmeyer Elizabeth C.,Cheng Eric,Wu Fan,Roberts Leo P.,Vesoulis Megan M.

Affiliation:

1. Department of Chemistry and Biochemistry, School of Green Chemistry and Engineering, The University of Toledo

Abstract

AbstractIodonium catalysis is described here to accomplish an intermolecular olefin oxyamination reaction. Urea is used as the O- and N-source to add across both activated and unactivated alkenes in a regioselective manner. Mechanistic studies confirm the presence of an iodonium intermediate.1 Introduction2 Hypothesis3 Optimizations and Scope4 Mechanistic Probes5 Future Outlook

Funder

National Institute of General Medical Sciences

University of Toledo

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1277-8669.pdf

Reference9 articles.

1. The Halogenation of Ethylenes

2. Development of Intramolecular Vicinal Diamination of Alkenes: From Palladium to Bromine Catalysis