Author:
Hayashi Minoru,Ohta Hidetoshi,Fujimoto Shion
Abstract
AbstractSynthesis of several heterocycle-fused λ5-phosphinines through intramolecular cyclization is described. The incorporation of a heteroatom affected their photophysical properties through perturbation of the LUMO level, which is in good contrast to the HOMO-based tuning by the C-4 substituent. The C-3-substituent-based property tuning provides a new guide to designing phosphinine-based fluorophores.
Funder
Japan Society for the Promotion of Science
Cited by
3 articles.
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