Synthesis of Carbamoyl Azides from Redox-Active Esters and TMSN3-Reference-Cited by-同舟云学术

Synthesis of Carbamoyl Azides from Redox-Active Esters and TMSN3

Published:2023-06-06 Issue: Volume: Page:
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Li Yajun¹,Bao Hongli¹^ORCID,Yuan Xiaobin²¹,Qu Yanjie²¹

Affiliation:

1. Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Chinese Academy of Sciences

2. College of Chemistry and Materials Science, Fujian Normal University

Abstract

AbstractAn efficient method for construction of C–N bonds is reported here. The iron-catalyzed azidation of N-hydroxy phthalimide (NHP) esters provides a convenient approach for the synthesis of carbamoyl azides with good substrate scope and functional group tolerance. Both aryl carbon C(sp2) and alkyl carbon C(sp3) sources can be used deliver the carbamoyl azides. Mechanistic studies were conducted and a two-stage process was identified.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Chinese Academy of Sciences

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-2106-5108.pdf

Reference39 articles.

1. Research Progress on Silver-Catalyzed Decarboxylative Coupling Reaction

2. Recent developments in decarboxylative cross-coupling reactions between carboxylic acids and N–H compounds

3. Photocatalysis in Dual Catalysis Systems for Carbon‐Nitrogen Bond Formation

4. Recent Developments in Photochemical and Electrochemical Decarboxylative C(sp3)–N Bond Formation

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1. A Mild Metal‐Free Approach for the Direct Synthesis of Carbamoyl Azides from Carboxylic Acid Redox Active Esters;Advanced Synthesis & Catalysis;2024-05-23