Photoinduced Organic Reactions by Employing Pyrene Catalysts

Author:

Sekine Kohei12,Kuninobu Yoichiro12ORCID,Shiozuka Akira1

Affiliation:

1. Interdisciplinary Graduate School of Engineering Sciences, Kyushu University

2. Institute for Materials Chemistry and Engineering, Kyushu University

Abstract

AbstractPyrene is one of the most attractive polycyclic aromatic hydrocarbons (PAHs) in photochemistry. Based on their redox properties, pyrenes have potential as photosensitizers. In this review, we summarize recent developments in pyrene-catalyzed photoinduced organic reactions occurring via energy transfer or single-electron transfer based on the excited state of the pyrene.1 Introduction2 Photolysis Involving N–O Bond Cleavage or Decarboxylation3 (Cyclo)addition Reactions with Styrenes4 Transformations via Cleavage of C–F, C–I, C–S and C–N Bonds5 Reactions Based on Sensitization-Initiated Electron Transfer (SenI­-ET)6 Miscellaneous Transformations7 Conclusion

Funder

Japan Society for the Promotion of Science

Yamada Science Foundation

The Sumitomo Foundation

Shorai Foundation for Science and Technology

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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