Author:
Yamada Yoichi M. A.,Matsukawa Yuta
Abstract
AbstractThe hydrogenolysis of iodoarenes using a silicon nanoarray palladium catalyst under microwave irradiation was investigated. When triethanolamine was used as the sacrificial reductant, the reaction proceeded via reductive deiodination under an aerobic atmosphere even without the presence of the explosive hydrogen gas, affording the corresponding hydrogen-substituted arenes in high yields. No reaction occurred in the absence of microwaves, indicating a noticeable microwave effect.
Funder
RIKEN
Japan Society for the Promotion of Science
Japan Agency for Medical Research and Development