Glycosylation of Stannyl Ceramides Promoted by Modified Montmorillonite in Supercritical Carbon Dioxide-Reference-Cited by-同舟云学术

Glycosylation of Stannyl Ceramides Promoted by Modified Montmorillonite in Supercritical Carbon Dioxide

Published:2017-11-07 Issue:03 Volume:50 Page:593-598
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Morales-Serna José¹^ORCID,Nguyen Bao²^ORCID,García-Ríos Eréndira³^ORCID,Gaviño Rubén³^ORCID,Cárdenas Jorge³^ORCID,García de la Mora Gustavo⁴

Affiliation:

1. Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa

2. School of Chemistry, University of Leeds, Leeds

3. Instituto de Química, Universidad Nacional Autónoma de México

4. Departamento de Química Orgánica, Facultad de Química, Universidad Nacional Autónoma de México

Abstract

The direct glycosylation of ceramides in supercritical carbon dioxide (scCO2) successfully proceeded to produce β-glycolipids in high yield and with full stereoselectivity. The reaction is promoted by montmorillonite modified with a superacid (CF3SO3H). The value of this protocol was demonstrated in the efficient synthesis of isoglobotrihexosylceramide (iGB3).

Funder

CONACyT

PRODEP-SEP

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1591515.pdf

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