Affiliation:
1. Institute of Organic Chemistry, Polish Academy of Sciences
Abstract
On the basis of previously published experimental studies and ab initio calculations, a general corrected mechanism of nucleophilic aromatic substitution was formulated. It was shown that conventional nucleophilic substitution of halogens is a slow secondary reaction whereas nucleophilic substitution of hydrogen is the fast primary process. The general mechanism embraces both of these alternative and complementary reactions.
Subject
Organic Chemistry,Catalysis
Cited by
32 articles.
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