A Convenient Synthesis of Fused Tetrahydroazocines from Acenaphthylene-1,2-dione, Proline, and Acetylenic Esters-Reference-Cited by-同舟云学术

A Convenient Synthesis of Fused Tetrahydroazocines from Acenaphthylene-1,2-dione, Proline, and Acetylenic Esters

Published:2017-12-11 Issue:05 Volume:29 Page:635-639
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Yavari Issa¹,Baoosi Leila¹,Halvagar Mohammad²

Affiliation:

1. Department of Chemistry, Tarbiat Modares University

2. Department of Inorganic Chemistry, Chemistry and Chemical Engineering Research Center of Iran

Abstract

A synthesis of dialkyl (12E,14E)-7-oxo-10,11-dihydro-7H,9H-azocino[2,1-a]benzo[de]isoquinoline-13,14-dicarboxylates through a 1,3-dipolar cycloaddition reaction of azomethine ylides, generated in situ from proline and acenaphthylene-1,2-dione, with dialkyl acetylenedicarboxylates is described. According to the X-ray diffraction data, the tetrahydroazocine ring has a rigid twist-boat form with approximate local C2 symmetry.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1591855.pdf

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