Abstract
AbstractStarting from readily available cyclic homoallylic alcohols, a Prins reaction allowed the formation of a bicyclic tetrahydropyranyl carbocation intermediate that is only trapped by electron-rich aromatic rings according a further intramolecular Friedel–Crafts reaction leading to new [4.4.3]propellane structures.
Funder
Ministère de l’Enseignement supérieur, de la Recherche et de l’Innovation
Centre National de la Recherche Scientifique
Université de Lyon 1
Subject
Organic Chemistry,Catalysis
Cited by
2 articles.
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