Electrochemical Aromatization of Dihydroazines: Effect of Chalco­genophosphoryl (CGP) Substituents on Anodic Oxidation of 9-CGP-9,10-dihydroacridine

Author:

Shchepochkin Alexander V.1ORCID,Chupakhin Oleg N.1ORCID,Demina Nadezhda S.1ORCID,Averkov Maxim A.1ORCID,Shimanovskaya Tatyana Yu.1,Slepukhin Pavel A.1ORCID,Volkov Pavel A.2,Telezhkin Anton A.2ORCID,Trofimov Boris A.2ORCID,Charushin Valery N.1ORCID

Affiliation:

1. Institute of Organic Synthesis of the Russian Academy of Sciences

2. A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Abstract

AbstractThe effect of chalcogenophosphoryl fragments on the anodic oxidation of 9-chalcogenophosphoryl-9,10-dihydroacridines was studied in detail. The data of X-ray structural analyses, quantum chemical calculations, and cyclic voltammetry measurements obtained for these compounds provide an explanation of the observed features. The direct electrochemical phosphorylation of acridine was first carried out successfully.

Funder

Russian Foundation for Basic Research

Russian Science Foundation

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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