Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions-Reference-Cited by-同舟云学术

Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions

Published:2023-09-07 Issue:01 Volume:35 Page:130-134
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Huang Junhai¹²,Hu Lianrui³,Xu Lin³,Zeng Zhi-Yong³,Zhao Xiaoli³,Zhu Jing⁴,Jin Tongxia³,Dou Wei-Tao³

Affiliation:

1. College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science

2. State Key Laboratory of New Drug and Pharmaceutical Process, Shanghai Institute of Pharmaceutical Industry, China State Institute of Pharmaceutical Industry

3. School of Chemistry and Molecular Engineering, East China Normal University

4. Department of Philosophy, East China Normal University

Abstract

AbstractFunctionalized metallacages have attracted tremendous attention in recent years due to their potential applications in optical sensing, catalysis, and recognition. A novel anthracene-functionalized metallacage was synthesized and characterized in detail by UV/vis spectroscopy, 1D/2D NMR, electrospray ionization time-of-flight mass spectrometry, and X-ray single crystal diffraction. This metallacage exhibited a specific fluorescence enhancement response to OH–, PO4 3–, and AcO– anions, and further analysis indicated that this was due to anion-induced metallacage disassembly.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0042-1751486.pdf

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