Green synthesis of ZnO nanoparticles and comparison of 2,4-dinitrophenol removal efficiency using photocatalytic, sonocatalytic, and adsorption processes

Abstract

In the present work, the extract of a paper-flower species called Bougainvillea spectabilis was used to green synthesis of ZnO nanoparticles (NPs). The synthesized ZnO NPs was confirmed by XRD, SEM, TEM, EDS, and FTIR techniques. Then, the ability of ZnO NPs to remove 2,4-dinitrophenol from aqueous solutions was investigated using photocatalytic and sonocatalytic processes. All experiments were carried out in a batch system and the effects of pH, NPs dosage, concentration, and contact time were evaluated. The findings of this study showed that the pseudo-second-order kinetic model could well describe the removal of 2,4-dinitrophenol by ZnO NPs. Langmuir, Freundlich, Temkin, and BE-T isotherm models were also assessed in a dark condition. The Freundlich isotherm model was able to provide the best fit with the experimental data. Examination of the results showed that the degradation of 2,4-dinitrophenol at the presence of ultraviolet (UV) and ultrasonic (US) waves was able to increase the removal efficiency to about twice as much as removal by adsorption alone. Also, The obtained results showed that the maximum removal of 2,4-dinitrophenol under photocatalytic and sonocatalytic conditions occurred at the presence of 25 mg of NPs, solution pH of 4, and 2,4-dinitrophenol concentration of 20 ppm. The best rates of photocatalytic and sonocatalytic degradation under the optimal conditions were 84.42% and 77.13% during 60 min, respectively. Thermodynamic studies indicated that the degradation of 2,4-dinitrophenol by ZnO NPs is a spontaneous and endothermic process in the direction of increasing entropy. The zinc oxide NPs have better performance in the removal of 2,4-dinitrophenol at the presence of UV and US waves.