Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands

Author:

Shariatinia Zahra,Asadi Ebadullah,Tavasolinasab Vahid,Gholivand Khodayar

Abstract

Four novel organotin(IV) complexes containing phosphoric triamide ligands were synthesized and characterized by multinuclear (1H, 31P, 13C) NMR, infrared, ultraviolet and fluorescence spectroscopy as well as elemental analysis. The 1H NMR spectra of complexes 14 proved that the Sn atoms adopt octahedral configurations. The nanoparticles of the complexes were also prepared by ultrasonication, and their SEM micrographs indicated identical spherical morphologies with particles sizes about 20–25 nm. The fluorescence spectra exhibited blue shifts for the maximum wavelength of emission upon complexation.

Publisher

Beilstein Institut

Subject

Electrical and Electronic Engineering,General Physics and Astronomy,General Materials Science

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