Author:
Shubina Tatyana E,Freund Matthias,Schenker Sebastian,Clark Timothy,Tsogoeva Svetlana B
Abstract
A new guanidine-thiourea organocatalyst has been developed and applied as bifunctional organocatalyst in the Michael addition reaction of diethyl malonate to trans-β-nitrostyrene. Extensive DFT calculations, including solvent effects and dispersion corrections, as well as ab initio calculations provide a plausible description of the reaction mechanism.
Cited by
39 articles.
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