Abstract
While significant research has investigated the processing and properties of high-performance terpolymer fibers, much remains to be understood about the internal nano- and microstructures of these fibers, and how these morphologies relate to fiber properties. Here we use a focused ion beam notch technique and multifrequency atomic force microscope mapping to characterize the internal structure and local mechanical properties within Technora® fibers. We find a highly fibrillated structure that appears to connect with both the fiber’s molecular chemistry and full-fiber mechanical properties. In addition, through detailed comparisons with Kevlar® K29 fibers, we find remarkable differences between the internal structures of the two fibers, and posit connections between our measurements and multifunctional performance studies from the literature.
Subject
Electrical and Electronic Engineering,General Physics and Astronomy,General Materials Science