Self-assembly of C60 on a ZnTPP/Fe(001)–p(1 × 1)O substrate: observation of a quasi-freestanding C60 monolayer

Abstract

Fullerene (C60) has been deposited in ultrahigh vacuum on top of a zinc tetraphenylporphyrin (ZnTPP) monolayer self-assembled on a Fe(001)–p(1 × 1)O substrate. The nanoscale morphology and the electronic properties of the C60/ZnTPP/Fe(001)–p(1 × 1)O heterostructure have been investigated by scanning tunneling microscopy/spectroscopy and ultraviolet photoemission spectroscopy. C60 nucleates compact and well-ordered hexagonal domains on top of the ZnTPP buffer layer, suggesting a high surface diffusivity of C60 and a weak coupling between the overlayer and the substrate. Accordingly, work function measurements reveal a negligible charge transfer at the C60/ZnTPP interface. Finally, the difference between the energy of the lowest unoccupied molecular orbital (LUMO) and that of the highest occupied molecular orbital (HOMO) measured on C60 is about 3.75 eV, a value remarkably higher than those found in fullerene films stabilized directly on metal surfaces. Our results unveil a model system that could be useful in applications in which a quasi-freestanding monolayer of C60 interfaced with a metallic electrode is required.