Author:
Hsu Mei-Yuan,Liu Yi-Pei,Lam Sarah,Lin Su-Ching,Wang Cheng-Chung
Abstract
The thio-additions of glycals were efficiently promoted by a stoichiometric amount of trimethylsilyl bromide (TMSBr) to produce S-2-deoxyglycosides under solvent-free conditions in good to excellent yields. In addition, with triphenylphosphine oxide as an additive, the TMSBr-mediated direct glycosylations of glycals with a large range of alcohols were highly α-selective.
Cited by
20 articles.
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