Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia-Reference-Cited by-同舟云学术

Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia

Published:2016-11-21 Issue: Volume:12 Page:2471-2477
ISSN:1860-5397
Container-title:Beilstein Journal of Organic Chemistry
language:en
Short-container-title:Beilstein J. Org. Chem.

Author:

Semakin Artem N,Kokuev Aleksandr O,Nelyubina Yulia V,Sukhorukov Alexey Yu,Zhmurov Petr A,Ioffe Sema L,Tartakovsky Vladimir A

Abstract

Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)amine to the respective 1,4,6,10-tetraazaadamantane derivative was demonstrated.

Publisher

Beilstein Institut

Subject

Organic Chemistry

Link

https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-12-241.pdf

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