Author:
Guidone Stefano,Nahra Fady,Slawin Alexandra M Z,Cazin Catherine S J
Abstract
The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1st generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands.
Cited by
5 articles.
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